I think that having a mod that opens the chat at specific times. Maybe you should assign certain mods certain hours to open chat? (several so that not one mod has to be worried)
But I also I wouldn't be happy with it I got to know a lot of users through chat and I think it's the best way people get to know each other because it is so instant. There is always MSN but I like chat better because I feel it is better than sharing my personal MSN with someone I don't know at all but want to get to know. I just feel it is safer.
One problem I see arising from this: If you open only on the weekends, the site will stall and the chat will be crowded. Since people are busy during the week and if they are distracted during the weekend by chat, I don't think it'll help much with site activity.
One thing I stick too though: Removing chat off the homepage. Putting it on "My YWS" is a smart idea so people will not join for the chatroom, or it will not be the first thing members see.
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